1597488-10-2Relevant academic research and scientific papers
Synthesis of the pluramycins 1: Two designed anthrones as enabling platforms for flexible Bis-C-glycosylation
Kitamura, Kei,Ando, Yoshio,Matsumoto, Takashi,Suzuki, Keisuke
supporting information, p. 1258 - 1261 (2014/03/21)
Two effective tricyclic platforms are reported for the installation of the two constituent sugars, l-vancosamine and d-angolosamine, in a regio- and stereoselective manner for the synthesis of the pluramycin class of bis-C-glycoside antitumor antibiotics. Two complementary protocols are now available that differ in the order in which the two sugar moieties are installed. Sc(OTf)3 was effective as the Lewis acid.
