159826-50-3Relevant academic research and scientific papers
Z-Stereoselective Peterson olefination of ketones
Grigorieva, N. Ya.,Pinsker, O. A.,Buevich, A. V.,Moiseenkov, A. M.
, p. 492 - 499 (2007/10/02)
A highly-stereoselective method (90percent of the Z-isomer) was developed for the Peterson olefination of ketones with nerylacetone (1) as an example.The method is based on the introduction of a PhS group, which is removed after completion of the reaction, at the ketone C(3) atom. - Keywords: olefination of ketones, stereoselective synthesis, Peterson reaction, 2Z- and 2E-4-phenylthiofarnesoles and 2Z- and 2E-4-phenylthiofarnesoates
