1599438-40-0

Basic information

• Product Name: 2-(4-fluorobenzyl)-2-o-tolylcyclopentanone
• CAS NO: 1599438-40-0
• Molecular Weight: 282.358
• Mol File: 1599438-40-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(4-fluorobenzyl)-2-o-tolylcyclopentanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(4-fluorobenzyl)-2-o-tolylcyclopentanone(1599438-40-0)
• EPA Substance Registry System: 2-(4-fluorobenzyl)-2-o-tolylcyclopentanone(1599438-40-0)

Safety Data

• Hazardous Substances Data: 1599438-40-0(Hazardous Substances Data)

Upstream product

• 74346-22-8 1-(1-bromovinyl)-2-methylbenzene 
• 1599438-26-2 1-(1-(o-tolyl)vinyl)cyclobutan-1-ol 

Relevant articles and documents

Dual visible light photoredox and gold-catalyzed arylative ring expansion

A combination of visible light photocatalysis and gold catalysis is applied to a ring expansion-oxidative arylation reaction. The reaction provides an entry into functionalized cyclic ketones from the coupling reaction of alkenyl and allenyl cycloalkanols with aryl diazonium salts. A mechanism involving generation of an electrophilic gold(III)-aryl intermediate is proposed on the basis of mechanistic studies, including time-resolved FT-IR spectroscopy.