1599470-76-4Relevant academic research and scientific papers
Mechanistic Studies on Garratt-Braverman Cyclization: The Diradical-Cycloaddition Puzzle
Das, Joyee,Bag, Subhendu Sekhar,Basak, Amit
, p. 4623 - 4632 (2016/07/06)
In this work, we present the results of extensive multiprong studies involving the fate of deuterium-labeled substrates, EPR, trapping experiments, and LA-LDI mass spectrometry to sort out the controversies relating to the mechanism of Garratt-Braverman c
Selectivity in Garratt-Braverman cyclization of aryl-/heteroaryl- substituted unsymmetrical bis-propargyl systems: Formal synthesis of 7′-desmethylkealiiquinone
Das, Joyee,Mukherjee, Raja,Basak, Amit
, p. 3789 - 3798 (2014/05/20)
Unsymmetrical bis-propargyl ethers and sulfonamides containing various combinations of aryl/heteroaryl substituents at the acetylene termini were synthesized, and their reactivity under basic conditions was studied. Moderate to high (chemo)selectivity was
