1599484-91-9

Basic information

• Product Name: C₃₈H₄₂N₄O₈S₂
• Synonyms: C₃₈H₄₂N₄O₈S₂
• CAS NO: 1599484-91-9
• Molecular Weight: 746.905
• Mol File: 1599484-91-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₃₈H₄₂N₄O₈S₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₃₈H₄₂N₄O₈S₂(1599484-91-9)
• EPA Substance Registry System: C₃₈H₄₂N₄O₈S₂(1599484-91-9)

Safety Data

• Hazardous Substances Data: 1599484-91-9(Hazardous Substances Data)

Upstream product

• 585-47-7 benzene-1,3-disulfonyl chloride 
• 58520-04-0 (1S,2S)-1,2-bis(4-methoxyphenyl)ethane-1,2-diamine 

Relevant articles and documents

Asymmetric transfer hydrogenation of aromatic ketones catalyzed by new chiral C2-symmetric bis(sulfonyl) tetraaza ligands complexed with [Ru(η6-p-cymene)Cl2]2 in water

In this report, a new series of C2-symmetric bis(sulfonyl) tetraaza ligands were synthesized from (1S,2S)-1,2-diarylethylenediamine analogues and tested in the asymmetric transfer hydrogenation (ATH) of aromatic ketones by complexing with [Ru(η6-p-cymene)Cl2]2 employing sodium formate as hydrogen source in neat water. A moderate to excellent conversion (～99.8 %) and overall satisfying enantioselectivity (～92.8 %) were obtained with varied electronic and steric effects of the substituents on ligands and substrates.