159977-40-9Relevant articles and documents
FORMATION OF BF2 CHELATES IN ACYLATION OF RESORCINOL AND 4-CYCLOHEXYLRESORCINOL WITH CARBOXYLIC ACIDS IN THE PRESENCE OF BF3-ETHER COMPLEX
Panasenko, A. I.,Polyanskaya, N. L.,Starkov, S. P.
, p. 611 - 613 (2007/10/02)
New chelates, 1-acyl-2-difluoroboroxy-4-hydroxybenzene and 1-acyl-2-difluoroboroxy-4-hydroxy-5-cyclohexylbenzene, were synthesized by acylation of resorcinol and 4-cyclohexylresorcinol with acetic, propionic, butyric, valeric, and phenylacetic acids, catalyzed by BF3*OEt2.On heating with aqueous alcohol, the chelates are hydrolyzed to the corresponding ketones.