1600-31-3

Basic information

• Product Name: Picryl azide
• Synonyms: 2,4,6-Trinitrophenylazide;Picryl azide
• CAS NO: 1600-31-3
• Molecular Formula: C₆H₂N₆O₆
• Molecular Weight: 254.11668
• Mol File: 1600-31-3.mol
• Article Data: 4

Chemical Properties

• Melting Point: 93°C
• Boiling Point: 397.33°C (rough estimate)
• Flash Point: °C
• Appearance: /
• Density: 1.8759 (rough estimate)
• Refractive Index: 1.7500 (estimate)
• CAS DataBase Reference: Picryl azide(CAS DataBase Reference)
• NIST Chemistry Reference: Picryl azide(1600-31-3)
• EPA Substance Registry System: Picryl azide(1600-31-3)

Safety Data

• Hazardous Substances Data: 1600-31-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C6H3N6O6/c7-9-8-6-4(11(15)16)1-3(10(13)14)2-5(6)12(17)18/h1-2,7H/q+1

Upstream product

• 88-74-4 2-nitro-aniline 
• 88-89-1 2,4,6-Trinitrophenol 
• 1516-58-1 o-azidonitrobenzene 
• 88-88-0 2,4,6-trinitrochlorobenzene 

Downstream Products

• 54948-87-7 P,P,P-triphenyl-N-(trinitrophenyl)phosphine imide 
• 54948-88-8 P,P,P-triphenyl-N-(2,4,6-trinitrophenyl)phosphazide 
• 126822-11-5 C₁₄H₁₈N₁₀O₆ 
• 76569-24-9 Bis-(2,3-dihydro-1H-pyrrolo[1,2-a]indol-9-yl)-diazene; compound with 2,4,6-trinitro-phenylamine 
• 17683-29-3 cyclooctylidene-2,4,6-trinitroaniline 
• 17683-31-7 exo-3-2',4',6'-trinitrophenyl-3-azatricyclo<3.2.1.0^2,4>octane 
• 2919-12-2 trinitro-2,4,6 diphenylamine 
• 606-35-9 1-methoxy-2,4,6-trinitrobenzene 
• 141461-51-0 (cycloheptylmethylidene)-2,4,6-trinitroaniline 
• 141461-52-1 2',4',6'-trinitrophenyl-trans-2-azabicyclo<6.1.0>nonane 
• 96694-50-7 2,2,3,3,5,7,9,9,10,10-Decamethyl-6,12-bis-(2,4,6-trinitro-phenyl)-1,4,8,11-tetraoxa-6,12-diaza-5λ⁵,7λ⁵-diarsa-dispiro[4.1.4.1]dodecane 
• 141461-55-4 (cyclooctylmethylidene)-2,4,6-trinitroaniline 
• 141461-49-6 cyclononylidene-2,4,6-trinitroaniline 
• 141461-54-3 2',4',6'-trinitrophenyl-trans-2-azabicyclo<7.1.0>decane 

Relevant articles and documents

Thermal behavior, decomposition mechanism and thermal safety of 5,7-diamino-4,6-dinitrobenzenfuroxan (CL-14)

Thermal decomposition kinetics and mechanism of the high-energetic material 5,7-diamino-4,6-dinitrobenzenfuroxan (CL-14) were determined by differential scanning calorimetry (DSC), rapid scanning Fourier transform infrared spectroscopy, and simultaneous thermogravimetric and DSC analyses, coupled with FT-IR and mass spectroscopy. To evaluate the thermal safety of 5,7-diamino-4,6-dinitrobenzenfuroxan (CL-14), its specific heat capacity (Cp) was measured by DSC, and thermal conductivity (λ) was estimated. Kinetic parameters and heat of exothermic decomposition reaction of CL-14 were obtained by analysis of DSC curves. Kinetic parameters used to evaluate the thermal safety of CL-14, such as self-accelerating decomposition temperature (TSADT), critical temperature of thermal explosion (Tb) and impact sensitivity (H50), were obtained. Results showed that for CL-14, TSADT?=?282.0?°C and Tb?=?307.9?°C, whereas H50?=?39.79?cm, revealing that CL-14 had better thermal safety and heat resistance than HMX, RDX and GNTO.

Influence of strain on chemical reactivity. Relative reactivity of torsionally strained double bonds in 1,3-dipolar cycloadditions

The addition of picryl azide to a series of mono- and bicyclic olefins including trans- cycloalkenes and bridgehead alkenes is reported. Secondary reaction products were identified, and their mechanism of formation was explained by an analysis relating th