16000-71-8Relevant academic research and scientific papers
SmI2-promoted cross coupling reaction of N-2-bromoethylphthalimide and carbonyl compounds: Synthesis of α-aryl-α′-hydroxy ketones
González-Rodríguez, Jorge,Soto, Martín,Soengas, Raquel G.,Rodríguez-Solla, Humberto
, (2020)
In this paper, we have disclosed the SmI2-mediated carbonyl-imide reductive cross coupling between N-2-bromoethylphthalimide and different aldehydes and ketones in the presence of anhydrous catalytic NiI2. This methodology provided a
Samarium(II)-mediated reaction of allylic phosphate esters with carbonyl compounds: A new method for "Umpolung" of allylic phosphates
Araki, Shuki,Hatano, Masahiro,Ito, Hirokazu,Butsugan, Yasuo
, p. 329 - 336 (2007/10/02)
Allylic phosphates allylate ketones and aldehydes in the presence of samarium(II) iodide.The coupling proceeds with the preservation of the olefin geometry ever, regio- and stereoselectivity are not high.
