16004-77-6

Basic information

• Product Name: 1,3,5,7-tetraaminoadamantane
• CAS NO: 16004-77-6
• Molecular Weight: 196.296
• Mol File: 16004-77-6.mol

Chemical Properties

• Melting Point: 193-195 °C
• Boiling Point: 355.6±10.0 °C(Predicted)
• Density: 1.319±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 1,3,5,7-tetraaminoadamantane(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3,5,7-tetraaminoadamantane(16004-77-6)
• EPA Substance Registry System: 1,3,5,7-tetraaminoadamantane(16004-77-6)

Safety Data

• Hazardous Substances Data: 16004-77-6(Hazardous Substances Data)

Usage

Uses

Used in Materials Science:
1,3,5,7-tetraaminoadamantane is used as a building block in materials science for its unique adamantane core structure, which contributes to the development of new materials with enhanced properties.
Used in Pharmaceutical Development:
1,3,5,7-tetraaminoadamantane is used as a precursor in pharmaceutical development due to its potential to form novel nitrogen-rich organic molecules that could have therapeutic applications.
Used in Chemical Compound Synthesis:
1,3,5,7-tetraaminoadamantane is used as a key intermediate in the synthesis of new chemical compounds, leveraging its amine functional groups for the creation of diverse chemical entities with potential applications in various industries.

Upstream product

• 16004-76-5 adamantane-1,3,5,7-tetracarboxamide 

Relevant articles and documents

Three-Dimensional Tetrathiafulvalene-Based Covalent Organic Frameworks for Tunable Electrical Conductivity

The functionalization of three-dimensional (3D) covalent organic frameworks (COFs) is essential to broaden their applications. However, the introduction of organic groups with electroactive abilities into 3D COFs is still very limited. Herein we report the first case of 3D tetrathiafulvalene-based COFs (3D-TTF-COFs) with non- or 2-fold interpenetrated pts topology and tunable electrochemical activity. The obtained COFs show high crystallinity, permanent porosity, and large specific surface area (up to 3000 m2/g). Furthermore, these TTF-based COFs are redox active to form organic salts that exhibit tunable electric conductivity (as high as 1.4 × 10-2 S cm-1 at 120 °C) by iodine doping. These results open a way toward designing 3D electroactive COF materials and promote their applications in molecular electronics and energy storage.

3D microporous base-functionalized covalent organic frameworks for size-selective catalysis

The design and synthesis of 3D covalent organic frameworks (COFs) have been considered a challenge, and the demonstrated applications of 3D COFs have so far been limited to gas adsorption. Herein we describe the design and synthesis of two new 3D microporous base-functionalized COFs, termed BF-COF-1 and BF-COF-2, by the use of a tetrahedral alkyl amine, 1,3,5,7-tetraaminoadamantane (TAA), combined with 1,3,5-triformylbenzene (TFB) or triformylphloroglucinol (TFP). As catalysts, both BF-COFs showed remarkable conversion (96 % for BF-COF-1 and 98 % for BF-COF-2), high size selectivity, and good recyclability in base-catalyzed Knoevenagel condensation reactions. This study suggests that porous functionalized 3D COFs could be a promising new class of shape-selective catalysts.