1600523-84-9Relevant academic research and scientific papers
Catalytic activity and selectivity of a range of ruthenium complexes tested in the styrene/EDA reaction system
Dragutan, Ileana,Ding, Fu,Sun, Ya-Guang,Verpoort, Francis,Dragutan, Valerian
, p. 86 - 94 (2014)
The complex ensemble of competing chemical processes (cyclopropanation, metathesis, dimerisation) involved in the reaction of ethyl diazoacetate with styrene is examined in the presence of a panel of ten ruthenium complexes. Our results, focusing on the catalysts' activity and selectivity, showcased the new NHC-containing complex 10 and the Fischer carbene 7 as leading to best chemoselectivities for cyclopropanation while the bidentate Schiff-base complexes 3 and 4 provided highest stereoselectivity. The traditionally metathesis-active Grubbs I catalyst (5) could be manipulated, by working under high dilution, to display moderate activity in cyclopropanation whereas the Grubbs II catalyst (6) totally promoted metathesis. Data obtained with the above set of Ru complexes strongly support the premise that ligand structure and configuration in the Ru coordination sphere are essential factors in controlling the reaction pathways.
