160066-47-7

Upstream product

• 108-98-5 thiophenol 
• 160066-41-1 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluoro-1-phenylsulfanyl-decan-2-ol 
• 52835-16-2 2-Heptadecafluorooctyl-oxirane 
• 160066-44-4 2-perfluorooctyl-2-hydroxyethyl phenyl sulfoxide 
• 74-88-4 methyl iodide 

Downstream Products

• 161080-32-6 2-perfluorooctyl-1-acetoxy-2-methoxyethyl phenyl sulfide 

Relevant academic research and scientific papers

Synthesis and Pummerer reaction of 2-F-alkyl-2-hydroxyethylphenyl sulfoxides

The synthesis of new 2-F-alkyl-2-hydroxyethylphenyl sulfoxides 3 and their 2-methyl ethers 4 is reported.They undergo the Pummerer rearrangement to yield 2-F-alkyl-1,2-diacetoxyethylphenyl sulfides 7 and 2-F-alkyl-1-acetoxy-2-methoxyethylphenyl sulfides 8

Synthesis of 3-F-alkyl-2-methoxy-3-phenylthiopropenals

The synthesis of 3-F-alkyl-2-methoxy-3-phenylthiopropenals has been realised by basic hydrolysis of acetylated sulfides of the type R(F)-CH(OCH3)-CH(OAc)-S-Ph. A reaction suite is proposed to explain the formation of these aldehydes which may prove useful precursors in synthesis of F-alkylated heterocyclic compounds.