1601477-13-7Relevant academic research and scientific papers
Metal-catalyzed dealkoxylative Caryl-C sp 3 cross-coupling - Replacement of aromatic methoxy groups of aryl ethers by employing a functionalized nucleophile
Leiendecker, Matthias,Hsiao, Chien-Chi,Guo, Lin,Alandini, Nurtalya,Rueping, Magnus
, p. 12912 - 12915 (2014)
The direct replacement of aromatic methoxy groups with activated carbon nucleophiles would give rise to novel synthetic pathways for targeted and diversity-oriented syntheses. We demonstrate here that this transformation can be achieved in a one-step reac
Pd-carbene migratory insertion: Application to the synthesis of trifluoromethylated alkenes and dienes
Wang, Xi,Xu, Yan,Deng, Yifan,Zhou, Yujing,Feng, Jiajie,Ji, Guojing,Zhang, Yan,Wang, Jianbo
supporting information, p. 961 - 965 (2014/02/14)
Pd-catalyzed cross-coupling of halides with CF3-substituted diazo compounds or N-tosylhydrazones has been explored for the synthesis of CF3-substituted alkenes and 1,3-butadienes. Pd-carbene migratory insertion plays the key role in these transformations. Copyright
