16020-36-3Relevant academic research and scientific papers
Novel nucleophilic rearrangement of 1-substituted isoquinolines using an alcoholic sodium hydroxide solution
Terenin,Volkov,Ivanov,Kabanova
experimental part, p. 74 - 81 (2011/12/21)
The reactions of 1-substituted isoquinolinium salts have been studied in the cases of the 1-isopropyl-2-methyl- and 2-methyl-1-cyclohexylisoquinolinium iodides using an alcoholic solution of sodium hydroxide. The possibility of preparing a wide range of spirocyclic ketones, alcohols, amino alcohols, and isochroman-3-ones has been demonstrated.
Influence of electron-donor sensitizers on SET-promoted photochemical reactions of β,γ-unsaturated aldehydes
Armesto, Diego,Ortiz, Maria J.,Agarrabeitia, Antonia R.,Martin-Fontecha, Mar
, p. 2261 - 2264 (2007/10/03)
β,γ-Unsaturated aldehydes undergo photochemical oxa-di-π-methane and decarbonylation reactions using DMN as an electron-donor sensitizer, whereas, using DMA, other photoproducts resulting from proton abstraction by ketyl- and alkene-centered radical-anion
