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16022-69-8

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16022-69-8 Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 93, p. 3538, 1971 DOI: 10.1021/ja00743a046

Check Digit Verification of cas no

The CAS Registry Mumber 16022-69-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,6,0,2 and 2 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 16022-69:
(7*1)+(6*6)+(5*0)+(4*2)+(3*2)+(2*6)+(1*9)=78
78 % 10 = 8
So 16022-69-8 is a valid CAS Registry Number.
InChI:InChI=1/C7H3Cl5O/c8-3-2(1-13)4(9)6(11)7(12)5(3)10/h13H,1H2

16022-69-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name (2,3,4,5,6-pentachlorophenyl)methanol

1.2 Other means of identification

Product number -
Other names pentachlorobenzyl alcohol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:16022-69-8 SDS

16022-69-8Relevant articles and documents

Activation Volumes for Intramolecular Oxidative C-X (X = H, F, Cl or Br) Addition to Platinum(II) Imine Complexes as a Proof of the Intimate Mechanism

Crespo, Margarita,Martinez, Manuel,Pablo, Esther de

, p. 1231 - 1236 (2007/10/03)

The kinetics of C-X (X=H, F, Cl or Br) bond activation of ring-substituted, PhCHNCH2Ph, type imines via intramolecular oxidative addition to platinum(II) complexes has been studied in acetone and toluene solution at different temperatures and pressures.Although the activation parameters determined are within the range expected, the latter is extremely large (ΔH from 25 to 70 kJ mol-1, ΔS from -220 to -45 J K-1 mol-1, ΔV from -3.12 to -9.5 cm3 mol-1).No differences were found for the reactions carried out in acetone or toluene, indicating that no planar transition state is formed during the reaction and that a common highly ordered three-centered C-Pt-X intraction is present for all the imines used.A good correlation was also obtained for the ΔS and ΔV values, independently of the solvent used, confirming the non-polarity of the transition state.A deviation from this pattern is observed only for fluorinated imines both in acetone and toluene solutions; this result is interpreted by considering an earlier transition state for the oxidative addition of C-F that has not yet produced an important volume contraction of the platinum centre despite the important spacial organization of the ligand, as shown by the very negative values of ΔS.

Thiolphosphoric acid-S-4-nitro-2-trichloromethylphenyl esters as fungicides

-

, (2008/06/13)

New thiolphosphoric acid-S-4-nitro-2-trichloromethylphenyl esters of the formula STR1 where X denotes oxygen or sulfur, and R1 and R2 are identical or different and each denotes a substituted or unsubstituted aliphatic radical of 1 to 18 carbon atoms or a substituted or unsubstituted alicyclic radical of 5 to 18 carbon atoms, processes for their manufacture, fungicides containing these compounds as active ingredients, their manufacture, and processes for combating fungi with these novel compounds.

N-(fluorodichloromethylthio)-benzanilides

-

, (2008/06/13)

New and valuable N-(fluorodichloromethylthio)-benzanilides, a process for their manufacture, fungicides containing these compounds as active ingredients, and a method of combatting fungi with these compounds.

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