160248-91-9Relevant academic research and scientific papers
A Convenient and Direct Route to Phosphinoalkynes via Copper-Catalyzed Cross-Coupling of Terminal Alkynes with Chlorophosphanes
Afanasiev, Vladimir V.,Beletskaya, Irina P.,Kazankova, Marina A.,Efimova, Irina V.,Antipin, Mikhail U.
, p. 2835 - 2838 (2003)
A new efficient method to obtain various alkynylphosphanes R nP(≡R′)3-n [R = Ar, Alk, alkoxy, amido R′ = Ar, Het, Alk, CH2Z (Z = OMe, NMe2), n = 0-2] has been developed by means of cross-coupling reaction of chl
Multigram Synthesis of Difluoromethylene Phosphonic and Phosphinic Amides and Phosphine Oxides via Formal [2,3]-Sigmatropic Allyl Phosphite-Allylphosphonate Rearrangement
Shevchuk, Michael,R?schenthaler, Gerd-Volker
, p. 171 - 183 (2021/09/13)
We describe a method for the preparation of CF2-P(V) building blocks and monomers for biological and materials chemistry applications in multigram quantities based on a formal [2,3]-sigmatropic phospha-Wittig rearrangement of readily available fluoroallyl
THIAZAPHOSPHOLIDINE. IV. THIAZAPHOSPHOLIDINSULFIDE UND -OXIDE, ETHINYLAMINOPHOSPHANE
Fluck, Ekkehard,Bieger, Klaus,Heckmann, Gernot,Weller, Frank,Boegge, Hartmut
, p. 59 - 78 (2007/10/02)
The synthesis of the ethinylaminophosphanes 1-5 from substituted alkinylmagnesium bromides and halogenoaminophosphanes is described.Reaction of 1 with various derivatives of urea yields the thiazaphospholidines 6, 7, 11-13, 2 reacts with thiouracil
