1602525-71-2Relevant academic research and scientific papers
Stereochemical investigation and total synthesis of inuloidin, a biologically active sesquiterpenoid from Heterotheca inuloides
Kamatani, Jumpei,Iwadate, Takehiro,Tajima, Reiko,Kimoto, Hideaki,Yamada, Yoichi,Masuoka, Noriyoshi,Kubo, Isao,Nihei, Ken-Ichi
, p. 3141 - 3145 (2014)
The stereochemistry of inuloidin (1), which was a sesquiterpenoid that was characterized as a plant growth inhibitory substance from Heterotheca inuloides, was investigated. The modified Mosher's method coupled with a total synthetic study using osmium oxidation and Burgess dehydration as key steps were performed to clarify the stereochemistry of 1, which was determined to be a 2S,4R isomer.
