1602882-48-3Relevant articles and documents
Manganese-catalyzed and promoted reactions of H-phosphinate esters
Fisher, Henry C.,Berger, Olivier,Gelat, Fabien,Montchamp, Jean-Luc
, p. 1199 - 1204 (2014)
H-Phosphinates react with alkenes and alkynes using catalytic manganese(II) acetate. Under stoichiometric conditions with manganese(III) acetate or with catalytic manganese(II) acetate+excess manganese(II) oxide various reactions like arylation or cyclization through radical oxidative arylation can take place. Whereas the chemistry of manganese is already well developed for the functionalization of H-phosphonates, the present methodology provides an unprecedented access to functionalized phosphinates in acceptable to good yields.