16031-58-6Relevant academic research and scientific papers
ELECTROCHEMICAL OXIDATION OF VICINAL DIOXIMES
Niyazymbetov, M. E.,Ul'yanova, E. V.,Petrosyan, V. A.
, p. 551 - 554 (1990)
First-wave oxidation of vicinal dioximes corresponds to the transfer of two electrons and two protons to give furoxans, which are further oxidized at the potentials of the second wave.It is shown that the key step in the electrochemical cylization of vici
Regioselective synthesis of C-nucleosides by 1,3-dipolar cycloaddition of arylnitrile oxides to 5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hex-5-enofuranose
Al-Timari, Usama A. R.,Fisera, Lubor
, p. 121 - 127 (2007/10/02)
The synthesis of 3-aryl-5-(1,2-O-isopropylidene-α-D-xylo-tetrofuranos-4-yl)-2-isoxazoline (3) from arylnitrile oxides and 5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hex-5-enofuranose (1) is described.The 1,3-dipolar cycloaddition reactions give mainly anti-adducts (>=95percent ?-facial stereoselectivity).
