160359-27-3Relevant academic research and scientific papers
A new simple synthesis of aryl-substituted 1,4-diketones
Kel'in, Alexander V.,Kulinkovich, Oleg G.
, p. 330 - 332 (1996)
1,4-Diketones have been prepared by aldol condensation of methyl ketones with α-bromo ketones in the presence of tert-butoxymagnesium or diethylamido magnesium bromide and subsequent rearrangement of the formed 4-bromo-3-hydroxy ketones under the action o
SYNTHESIS OF 1,4-DIKETONES, 3,4-EPOXY KETONES, AND 2,4-DISUBSTITUTED FURANS BASED ON THE PRODUCTS FROM CONDENSATION OF THE MAGNESIUM ENOLATES OF KETONES WITH α-BROMO KETONES
Kel'in, A. V.,Kulinkovich, O. G.
, p. 202 - 206 (2007/10/02)
4-Bromo-3-hydroxy ketones were obtained by the condensation of methyl ketones with 2-bromo ketones in the presence of tert-butoxymagnesium bromide or by the action of organomagnesium compounds on 2-bromo ketones.The reaction of 4-bromo-3-hydroxy ketones w
