16040-26-9Relevant academic research and scientific papers
Reactions of Trifluoromethyl Radicals. VI. Hydrogen Abstraction from Trifluoroacetic Acid and Trifluoroacetic (2H1)Acid
Arthur, Neville L.,David, Lennie F.
, p. 1535 - 1538 (2007/10/02)
The hydrogen abstraction reactions of CF3 radicals with CF3COOH and CF3COOD; CF3 + CF3COOH -> CF3H + CF3COO (1), CF3 + CF2COOD -> CF3D + CF3COO (2) have been studied in the temperature ranges 102-225 deg C and 153-275 deg C respectively.The rate constants, based on the value of 1013.36 cm3mol-1s-1 for the recombination of CF3 radicals, are given by (k in cm3 mol-1 s-1 and E in J mol-1): logk1 = (10.17 +/- 0.12) - (33140 +/- 970)/19.145T, logk2 = (9.51 +/- 0.11) - (46090 +/- 1010)/19.145T.
