1604016-75-2Relevant academic research and scientific papers
Construction of homoallylic alcohols from terminal alkynes and aldehydes with installation of syn-stereochemistry
Miura, Tomoya,Nishida, Yui,Murakami, Masahiro
supporting information, p. 6223 - 6226 (2014/05/20)
A cationic rhodium(I) catalyst turns 2-silyl-1-alkenylboronate, readily prepared from a terminal alkyne, into the corresponding allylboronate species, which immediately undergoes nucleophilic addition to an aldehyde to give a syn-homoallylic alcohol stereoselectively.
