160422-65-1Relevant articles and documents
6-hydroxymethyl-1,2,4-trioxanes and derivatives: An alternative 1,2,4-trioxane synthesis from β′γ′-unsaturated β-hydroxyhydroperoxides
Bloodworth,Johnson, Karen A.
, p. 8057 - 8060 (2007/10/02)
Allylic hydroperoxides CH2:C(Ph)CH(OOH)CH2OX (X = H, CONHPh, Ac), from regiospecific photooxygenation of allylic alcohols CH3C(Ph):CHCH2OX, form hemiperoxyacetals with aldehydes or ketones which upon cyclisation with mercury(II) trifluoroacetate then reduction with sodium borohydride diastereoselectively afford 1,2,4-trioxanes with XOCH2 substituents at C-6.