1604807-26-2Relevant academic research and scientific papers
AuCl3 catalyzed [3 + 2 + 1] cycloaddition: First use of aldehyde as a carbon monoxide-like one carbon synthon for triple C-C coupling
Gayen, Krishnanka S.,Maiti, Dilip K.
, p. 10204 - 10207 (2014)
A new [3 + 2 + 1] cycloaddition strategy is demonstrated using an aldehyde, an aldimine of a glycine ester and a terminal triple bond with AuCl3 catalyst. Aldehyde is exploited as the first alternative to the crucial partner CO for triple C-C coupled annulation for the synthesis of novel fused-tricyclic heterocycles.
