1605306-07-7Relevant academic research and scientific papers
E-H (E = R3Si or H) bond activation by B(C6F 5)3 and heteroarenes; Competitive dehydrosilylation, hydrosilylation and hydrogenation
Curless, Liam D.,Clark, Ewan R.,Dunsford, Jay J.,Ingleson, Michael J.
supporting information, p. 5270 - 5272 (2014/05/06)
In the presence of B(C6F5)3 five-membered heteroarenes undergo dehydrosilylation and hydrosilylation with silanes. The former, favoured on addition of a weak base, produces H2 as a by-product making the process catalytic in B(C6F5) 3 but also enabling competitive heteroarene hydrogenation. the Partner Organisations 2014.
