160602-69-7

Basic information

• Product Name: [Os(1,1,1,5,5,5-hexafluoro-3-azapentane-2,4-diiminato)H(CO)(PPh₃)2]
• CAS NO: 160602-69-7
• Molecular Weight: 949.87
• Mol File: 160602-69-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Os(1,1,1,5,5,5-hexafluoro-3-azapentane-2,4-diiminato)H(CO)(PPh₃)2](CAS DataBase Reference)
• NIST Chemistry Reference: [Os(1,1,1,5,5,5-hexafluoro-3-azapentane-2,4-diiminato)H(CO)(PPh₃)2](160602-69-7)
• EPA Substance Registry System: [Os(1,1,1,5,5,5-hexafluoro-3-azapentane-2,4-diiminato)H(CO)(PPh₃)2](160602-69-7)

Safety Data

• Hazardous Substances Data: 160602-69-7(Hazardous Substances Data)

Upstream product

• 36179-61-0 carbonyldihydridotris(triphenylphosphine)osmium 
• 675-05-8 trifluoroacetamidine 

Relevant articles and documents

Complexes of the Platinum Metals. Part 46. 1,1,1,5,5,5-Hexafluoro-3-azapentane-2,4-diiminato Derivatives of Ruthenium, Osmium and Iridium. Crystal Structure of

Trifluoroacetamidine, NH=C(CF3)-NH2, underwent a condensation reaction in the presence of certain platinum metal hydrides in boiling toluene to liberate ammonia and form complexes containing the N,N'-chelating 1,1,1,5,5,5-hexafluoro-3-azapentane-2,4-diiminate ligand NHC(CF3)NC(CF3)NH.Complexes prepared in this manner were , , (M = Ru or Os) and .Under similar conditions reacted to afford the complex in which intramolecular hydrogen bonding between the non-co-ordinated oxygen of the monodentate trifluoroacetate ligand and the adjacent NH moiety has been detected.An X-ray crystallographic study performed on has confirmed an octahedral ruthenium(II) structure with trans-phosphine ligands and a chelating NHC(CF3)NC(CF3)NH(1-) moiety.