160624-13-5Relevant academic research and scientific papers
Caesium Tetrathiafulvalene-thiolates: Key Synthetic Intermediates
Becher, Jan,Lau, Jesper,Leriche, Philippe,Moerk, Pernille,Svenstrup, Niels
, p. 2715 - 2716 (1994)
Treatment of cyanoethylated tetrathiafulvalene-thiolates or cyanoethylated 1,3-dithiole-2-thione-4,5-dithiolate with one equiv. of caesium hydroxide hydrate selectively and in high yield produces the corresponding monocaesium salts, which can subsequently
Sequential functionalisation of bis-protected tetrathiafulvalene-dithiolates
Simonsen, Klaus B.,Svenstrup, Niels,Lau, Jesper,Simonsen, Ole,Mork, Pernille,Kristensen, Gitte J.,Becher, Jan
, p. 407 - 418 (2007/10/03)
The utilisation of the 2-cyanoethyl group as a versatile protecting group for 2-thioxo-1,3-dithiole-4,5-dithiolates and tetrathiafulvalene-thiolates is reported. Mono deprotection of bis-protected 2-thioxo-1,3-dithiole-4,5-dithiolate and of bis-protected
Bis(trisubstituted tetrathiafulvalenyl) disulfides: Disulfide-bridged TTF dimers
Leriche, Philippe,Giffard, Michel,Riou, Amedee,Majani, Jean-Philippe,Cousseau, Jack,Jubault, Michel,Gorgues, Alain,Becher, Jan
, p. 5115 - 5118 (2007/10/03)
The title compounds are synthesized, using the oxidative coupling of TTF thiolates. The disulfide linkage induces approximate orthogonality between the two TTF units, while maintaining virtually unchanged their electrochemical properties.
