1606590-66-2

Basic information

• Product Name: C₁₅H₂₀F₃IO₆SSi
• CAS NO: 1606590-66-2
• Molecular Weight: 540.371
• Mol File: 1606590-66-2.mol

Chemical Properties

• CAS DataBase Reference: C₁₅H₂₀F₃IO₆SSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₅H₂₀F₃IO₆SSi(1606590-66-2)
• EPA Substance Registry System: C₁₅H₂₀F₃IO₆SSi(1606590-66-2)

Safety Data

• Hazardous Substances Data: 1606590-66-2(Hazardous Substances Data)

Upstream product

• 1402160-72-8 methyl 4-iodo-3,5-bis(((trifluoromethyl)sulfonyl)oxy)benzoate 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Relevant articles and documents

Divergent syntheses of fused β-naphthol and indene scaffolds by rhodium-catalyzed direct and decarbonylative alkyne-benzocyclobutenone couplings

A tunable rhodium-catalyzed intramolecular alkyne insertion reaction proceeding through the C-C cleavage of benzocyclobutenones is described. Selective formation of either the direct or decarbonylative insertion product can be controlled by using different catalytic systems. A variety of fused β-naphthol and indene scaffolds were obtained in good yields with high functional group tolerance. This work illustrates a divergent approach to synthesize fused-ring systems by C-C activation/functionalization. Cat. in control: A tunable rhodium-catalyzed intramolecular alkyne insertion reaction proceeding through C-C cleavage of benzocyclobutenones is described. Selective formation of either the direct or decarbonylative insertion product can be controlled by using different catalytic systems. A variety of fused β-naphthol and indene scaffolds were obtained in good yields with high functional-group tolerance. Copyright