160666-77-3Relevant academic research and scientific papers
Cyclometallation of Azine Phosphines of Type Z,E-PPh2CH2(t-Bu)=N-N=CHR (R = an Aromatic or Heterocyclic Group) involving X-Y (X = C, N or O; Y = H, I or Br) Bond Fission by Platinum(II)
Perera, Sarath D.,Shaw, Bernard L.
, p. 641 - 648 (2007/10/02)
The phosphino hydrazone Z-PPh2CH2C(t-Bu)=NNH2 1 is shown to be a convenient 'reagent' for converting aryl or heterocyclic aldehydes into azines which can rhen be cycloplatinated readily with C-H, C-I, C-Br, N-H or O-H bond fission.Condensation of 1 with b
Terdentate (P-N-O) Complexes formed from Z,E-PPh2CH2C(t-Bu)=N-N=CH(C6H4OH-2) or Z,E-PPh2CH2C(t-Bu)=N-N=CH and Nickel, Palladium, Platinum, Rhodium or Iridium
Hii, King Kuok,Perera, Sarath D.,Shaw, Bernard L.
, p. 3589 - 3596 (2007/10/02)
Condensation of Z-PPh2CH2C(t-Bu)=NNH2 with salicylaldehyde or 4,6-dimethoxysalicylaldehyde gave the azine phosphines Z,E-PPh2CH2C(t-Bu)=N-N=CH(C6H4OH-2) 1a or Z,E-PPh2CH2C(t-Bu)=N-N=CH 1b, respectively.Treatment of 1a with PdCl2(cod
