1606994-07-3Relevant academic research and scientific papers
Synthesis, structural characterization, and reactivity studies of 5-CF 3SO3-B10H13
Berkeley, Emily R.,Ewing, William C.,Carroll, Patrick J.,Sneddon, Larry G.
, p. 5348 - 5358 (2014/06/09)
In contrast to previous reactions carried out in cyclopentane solvent at room temperature that produced 6-TfO-B10H13 (TfO = CF 3SO3), the reaction of closo-B10H 102- with a large excess of trifluoromethanesulfonic acid in the ionic liquid 1-butyl-3-methylimidazolium trifluoromethanesulfonate (bmimOTf) gave exclusively the previously unknown 5-TfO-B10H 13 isomer. Experimental and computational studies demonstrated that the difference in the products of the two reactions is a result of 6-TfO-B 10H13 isomerizing to 5-TfO-B10H13 above room temperature in bmimOTf solutions. Reactivity studies showed that 5-TfO-B10H13: (1) is deprotonated by reaction with 1,8-bis(dimethylamino)naphthalene to form the 5-TfO-B10H 121- anion; (2) reacts with alcohols to produce 6-RO-B10H13 boryl ethers (R = Me and 4-CH 3O-C6H4); (3) undergoes olefin-hydroboration reactions to form 5-TfO-6,9-R2-B10H11 derivatives; and (4) forms a 5-TfO-6,9-(Me2S)2-B 10H11 adduct at its Lewis acidic 6,9-borons upon reaction with dimethylsulfide. The 5-TfO-6,9-(Me2S)2-B 10H11 adduct was also found to undergo alkyne-insertion reactions to form a range of previously unreported triflate-substituted 4-TfO-ortho-carboranes (1-R-4-TfO-1,2-C2B10H10) and reactions with triethylamine or ammonia to form the first TfO-substituted decaborate [R3NH+]2[2-TfO-B10H 92-], and [R3NH+] 2[1-TfO-B10H92-] (R = H, Et) salts.
