1607437-40-0

Basic information

• Product Name: dimethyl 2-allyl-2-((S,E)-1-nitro-4-phenylbut-3-en-2-yl)malonate
• Synonyms: dimethyl 2-allyl-2-((S,E)-1-nitro-4-phenylbut-3-en-2-yl)malonate
• CAS NO: 1607437-40-0
• Molecular Weight: 347.368
• Mol File: 1607437-40-0.mol

Chemical Properties

• CAS DataBase Reference: dimethyl 2-allyl-2-((S,E)-1-nitro-4-phenylbut-3-en-2-yl)malonate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl 2-allyl-2-((S,E)-1-nitro-4-phenylbut-3-en-2-yl)malonate(1607437-40-0)
• EPA Substance Registry System: dimethyl 2-allyl-2-((S,E)-1-nitro-4-phenylbut-3-en-2-yl)malonate(1607437-40-0)

Safety Data

• Hazardous Substances Data: 1607437-40-0(Hazardous Substances Data)

Upstream product

• 40637-56-7 dimethyl allylmalonate 
• 28925-75-9 1-nitro-4-phenylbutadiene 

Relevant articles and documents

A highly regio- and enantioselective organocatalyzed Michael addition of malonates to nitrodienes

An organocatalyzed direct Michael addition of unsubstituted/substituted malonates, acetoacetate, or acetylacetones to conjugated nitrodienes using a cinchona alkaloid-based thiourea catalyst is disclosed. The addition products were formed in high yields and regioselectivity. The enantioselectivities of the addition products were high in most cases and could significantly be improved upon by a single recrystallization. The addition products easily undergo chemoselective nitro group reduction and subsequent lactamization with a high synthetic potential.