1607446-82-1Relevant academic research and scientific papers
Mechanistic insights into hydroacylation with non-chelating aldehydes
Murphy, Stephen K.,Bruch, Achim,Dong, Vy M.
, p. 174 - 180 (2015)
The combination of a small-bite-angle diphosphine bis(dicyclohexylphosphino)methane (dcpm) and [Rh(cod)OMe]2 catalyses the hydroacylation of 2-vinylphenols with a wide range of non-chelating aldehydes. Here we present a detailed experimental st
Substrate-directed hydroacylation: Rhodium-catalyzed coupling of vinylphenols and nonchelating aldehydes
Murphy, Stephen K.,Bruch, Achim,Dong, Vy M.
, p. 2455 - 2459 (2014/03/21)
We report a protocol for the hydroacylation of vinylphenols with aryl, alkenyl, and alkyl aldehydes to form branched products with high selectivity. This cross-coupling yields α-aryl ketones that can be cyclized to benzofurans, and it enables access to eu
