1607449-26-2Relevant academic research and scientific papers
Neutral hexacoordinate silicon(IV) complexes with a tridentate dianionic O,N,X ligand (X = O, N, S), bidentate monoanionic X,N ligand (X = O, S), and phenyl ligand: Compounds with a SiO3N2C, SiSO 2N2C, SiO2N3C, SiSON3C, or SiS2ON2C skeleton
Wei?, J?rg,Baus, Johannes A.,Burschka, Christian,Tacke, Reinhold
, p. 2449 - 2455 (2014/06/09)
A series of neutral hexacoordinate silicon(IV) complexes (4a, 4b, 5a, 5b, 6a, and 6b) with a SiO3N2C, SiSO2N 2C, SiO2N3C, SiSON3C, or SiS 2ON2C skeleton have been synthesized and structurally characterized by solid-state and solution NMR spectroscopy and single-crystal X-ray diffraction. These studies were performed with a special emphasis on comparing the respective O/NMe/S analogues 4a/5a/6a and 4b/5b/6b and the O/S pairs 4a/4b, 5a/5b, and 6a/6b with respect to their structures and NMR spectroscopic parameters. A series of neutral hexacoordinate silicon(IV) complexes have been synthesized and structurally characterized by NMR spectroscopy and single-crystal X-ray diffraction. These studies were performed with a special emphasis on comparing the respective O/NMe/S analogues 4a/5a/6a and 4b/5b/6b and the O/S pairs 4a/4b, 5a/5b, and 6a/6b with respect to their structures and NMR spectroscopic parameters. Copyright
