1607479-71-9Relevant articles and documents
Rhodium-catalyzed [2+2+2] cycloaddition of diynes with carbodiimides and carbon dioxide under ambient conditions
Ishii, Masahiro,Mori, Fumiya,Tanaka, Ken
supporting information, p. 2169 - 2174 (2014/03/21)
It has been established that a cationic rhodium(I)/H8-binap complex is able to catalyze the [2+2+2] cycloaddition of diynes with carbodiimides and carbon dioxide under ambient conditions. Enantio- and/or regioselective variants of these reactions are also disclosed. Turn around: It has been established that a cationic rhodium(I)/H8-binap complex is able to catalyze the [2+2+2] cycloaddition of diynes with carbodiimides and carbon dioxide under ambient conditions. Enantio- and/or regioselective variants of these reactions are also disclosed. Copyright