1607804-89-6Relevant academic research and scientific papers
Construction of Six-Membered Silacyclic Skeletons via Platinum-Catalyzed Tandem Hydrosilylation/Cyclization with Dihydrosilanes
Long, Peng-Wei,Bai, Xing-Feng,Ye, Fei,Li, Li,Xu, Zheng,Yang, Ke-Fang,Cui, Yu-Ming,Zheng, Zhan-Jiang,Xu, Li-Wen
, p. 2825 - 2830 (2018)
Catalytic silicon-carbon or silicon-heteroatom bond-forming hydrosilylation has become increasingly important in synthetic chemistry, catalysis and organosilicon chemistry. Herein we report a platinum-catalyzed one-pot and tandem hydrosilylation/cyclization of OH-containing alkynes with dihydrosilanes, allowing for facile synthesis of six-membered organosilicon compounds, including silyloxycycles and cyclic siloxanes in high yields and with good stereoselectivities. (Figure presented.).
