160798-12-9

Basic information

• Product Name: Bicyclo[2.2.1]heptane-2-carboxylic acid, 2-amino-6-(methylthio)-, (2-endo,6-exo)- (9CI)
• Synonyms: Bicyclo[2.2.1]heptane-2-carboxylic acid, 2-amino-6-(methylthio)-, (2-endo,6-exo)- (9CI)
• CAS NO: 160798-12-9
• Molecular Formula: C9H15NO2S
• Molecular Weight: 201.2859
• Product Categories: AMINOACID
• Mol File: 160798-12-9.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Bicyclo[2.2.1]heptane-2-carboxylic acid, 2-amino-6-(methylthio)-, (2-endo,6-exo)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.1]heptane-2-carboxylic acid, 2-amino-6-(methylthio)-, (2-endo,6-exo)- (9CI)(160798-12-9)
• EPA Substance Registry System: Bicyclo[2.2.1]heptane-2-carboxylic acid, 2-amino-6-(methylthio)-, (2-endo,6-exo)- (9CI)(160798-12-9)

Safety Data

• Hazardous Substances Data: 160798-12-9(Hazardous Substances Data)

Upstream product

• 694-97-3 5-norbornene-2-ol 
• 139689-84-2 (1R,2R,4S,6R)-6-Methanesulfonyl-bicyclo[2.2.1]heptan-2-ol 
• 139757-85-0 (1R,2R,4S,6R)-6-Methylsulfanyl-bicyclo[2.2.1]heptan-2-ol 
• 139689-86-4 tert-Butyl-((1S,2S,4R,6S)-6-methanesulfonyl-bicyclo[2.2.1]hept-2-yloxy)-dimethyl-silane 
• 139689-76-2 6-endo-(methylthio)bicyclo[2.2.1]heptan-2-one 
• 139689-82-0 5-endo-(methylsulfonyl)-2-norbornene 
• 139689-93-3 C₁₀H₁₄N₂O₂S 
• 64887-94-1 Methyl 6-endo-(Methylthio)bicyclo<2.2.1>heptane-2-endo-carboxylate 
• 127572-42-3 methyl 2-exo-amino-6-endo-(methylthio)bicyclo<2.2.1>heptane-2-endo-carboxylate 

Downstream Products

• 127572-45-6 (1R,2R,4S,6R)-2-Benzoylamino-6-((S)-methanesulfinyl)-bicyclo[2.2.1]heptane-2-carboxylic acid methyl ester 
• 127572-45-6 (1R,2R,4S,6R)-2-Benzoylamino-6-((R)-methanesulfinyl)-bicyclo[2.2.1]heptane-2-carboxylic acid methyl ester 

Relevant articles and documents

Conformationally constrained amino acids: A concise route to a methionine analogue

A facile and concise synthesis of (±)-2-endo-amino-6-exo-(methylthio)[2.2.1]heptane-2-exo- carboxylic acid starting from the commercially available 5-norbornen-2-ol is decribed.

Synthesis and Crystal and Molecular Structure of the Conformationally Restricted Methionine Analogue. (+/-)-2-exo-Amino-6-endo-(methylthio)bicycloheptane-2-endo-carboxylic Acid and Neighboring Group Participation in Its Anodic Oxidation

(+/-)-2-exo-Amino-6-endo-(methylthio)bicycloheptane-2-endo-carboxylic acid (1c) was synthesized by amination of the lithium enolate of methyl 6-endo-(methylthio)bicycloheptane-2-endo-carboxylate with O-(mesitylensulfonyl)hydroxylamine follow