1608462-21-0

Basic information

• Product Name: 1-(1-cyclopropylbut-3-enyl)-4-methoxybenzene
• Synonyms: 1-(1-cyclopropylbut-3-enyl)-4-methoxybenzene
• CAS NO: 1608462-21-0
• Molecular Weight: 202.296
• Mol File: 1608462-21-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-(1-cyclopropylbut-3-enyl)-4-methoxybenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(1-cyclopropylbut-3-enyl)-4-methoxybenzene(1608462-21-0)
• EPA Substance Registry System: 1-(1-cyclopropylbut-3-enyl)-4-methoxybenzene(1608462-21-0)

Safety Data

• Hazardous Substances Data: 1608462-21-0(Hazardous Substances Data)

Upstream product

• 762-72-1 allyl-trimethyl-silane 
• 6552-45-0 α-cyclopropyl(4-methoxyphenyl)methanol 

Relevant articles and documents

Iron-catalyzed π-activated C-O ether bond cleavage with C-C and C-H bond formation

A novel and efficient allylic alkylation reaction between π-activated ethers and allylsilane was realized under mild conditions through iron(III)-catalyzed C sp 3-O ether bond cleavage. The present protocol provides an attractive approach for the construction of sp3-sp3 C-C bonds and can be potentially applied for the selective reduction of benzyl and allyl ethers to their corresponding hydrocarbon compounds by using triethylsilane as a hydride-transfer reagent. A mild, economical, and environmentally friendly method for the construction of C sp 3-C sp 3 bonds through iron-catalyzed π-activated C-O ether bond cleavage is developed. In addition, this catalytic system can be used for the selective reduction of benzylic and allylic C-O ether bonds to C-H bonds. Copyright