160847-27-8Relevant academic research and scientific papers
A Convenient One-pot Synthesis of Polyenic Enol Ethers
Vo-Quang, Yen,Carniato, Denis,Vo-Quang Liliane,Goffic, Francois Le
, p. 1505 - 1506 (1983)
Diethyl alkoxymethylphosphonates react with unsaturated aldehydes to give polyenic enol ethers with a good stereoselectivity.
Visible-Light Controlled Divergent Catalysis Using a Bench-Stable Cobalt(I) Hydride Complex
Beltran, Frédéric,Bergamaschi, Enrico,Teskey, Christopher J.
supporting information, p. 5180 - 5184 (2020/04/22)
While the use of visible light in conjunction with transition metal catalysis offers powerful opportunities to switch between on/-off states of catalytic activity, the next frontier would be the ability to switch the actual function of the catalyst and resulting products. Here we report such an example of multi-dimensional catalysis. Featuring an easily prepared, bench-stable cobalt(I) hydride complex in conjunction with pinacolborane, we can switch the reaction outcome between two widely employed transformations, olefin migration and hydroboration, with visible light as the trigger.
Encapsulated molecular catalysts in polysiloxane gels: Ruthenium cluster-catalyzed isomerization of alkenes
Motoyama, Yukihiro,Abe, Motonori,Kamo, Kazuyuki,Kosako, Yusuke,Nagashima, Hideo
supporting information; experimental part, p. 5321 - 5323 (2009/03/11)
Novel ruthenium-encapsulating polysiloxane gels are prepared by treatment of polymethylhydrosiloxane with diols in the presence of (μ3, η2,η3,η5-acenaphthylene)Ru 3(CO)7, and act as reusable catalysts in the isomerization of alkenes without leakage of the catalyst species. The Royal Society of Chemistry.
