16088-84-9

Usage

InChI:InChI=1/C26H47N/c1-3-5-7-9-11-13-15-20-24-27(26-22-18-17-19-23-26)25-21-16-14-12-10-8-6-4-2/h17-19,22-23H,3-16,20-21,24-25H2,1-2H3

Upstream product

• 112-30-1 1-Decanol 
• 62-53-3 aniline 

Downstream Products

• 1613306-94-7 4,4'-(10-decyl-10H-phenothiazine-3,7-diyl)bis(ethyne-2,1-diyl)bis(N,N-didecylaniline) 
• 752202-96-3 4-(didecylamino)phenylacetylene 
• 1613306-96-9 N,N-didecyl-4-((trimethylsilyl)ethynyl)aniline 
• 1613306-95-8 N,N-didecyl-4-iodoaniline 
• 1613307-00-8 4,4'-(10-decyl-5,5-dioxide-10H-phenothiazine-3,7-diyl)bis-(ethyne-2,1-diyl)bis(N,N-didecylaniline) 
• 1613306-99-2 4,4'-(10-decyl-5-oxide-10H-phenothiazine-3,7-diyl)bis(ethyne-2,1-diyl)bis(N,N-didecylaniline) 
• 116854-19-4 4-didecylaminobenzaldehyde 

Relevant academic research and scientific papers

Cobalt-Rhodium Heterobimetallic Nanoparticle-Catalyzed N-Alkylation of Amines with Alcohols to Secondary and Tertiary Amines

Without the requirement for base or other additives, Co2Rh2/C can selectively catalyze both mono- and bis-N-alkylation through the coupling of simple alcohols with amines, yielding a range of secondary and tertiary amines in good to excellent isolated yields. The reaction can be applied to benzyl alcohol with optically active 1-phenylethan-1-amines, and secondary amines were isolated in quantitative yields with an excellent enantiomeric excess (ee > 94%). Selectivity is achieved by varying the reaction temperature and amount of catalyst used. This catalytic system has several advantages including eco-friendliness and a simple workup procedure. The catalyst can be successfully recovered and reused ten times without any significant loss of activity.

Palladium catalyzed N-alkylation of amines with alcohols

An iron oxide immobilized palladium catalyst was prepared for the N-alkylation of amines with alcohols under base and organic ligand free conditions. Applying the optimized reaction conditions, the coupling reactions of amines and alcohols with various structures could be realized with up to 99% isolated yields. The catalysts were studied by XRD, BET, and XPS and the mechanism was studied by DFT calculations.