1609090-75-6Relevant academic research and scientific papers
Bis(alkyl) yttrium complex containing a new tridentate amidinate ligand: Synthesis and structure
Yakovenko,Cherkasov,Fukin,Trifonov
, p. 1772 - 1776 (2014/07/07)
New potentially tridentate amidine containing the quinoline fragment in the lateral chain, viz., NC9H6-8-NHC(But)N-2,6- Pri-2-C6H3 (1), was synthesized by the reaction of chloroimine 2,6-Pri 2-C6H 3-N=C(But)Cl and lithium derivative of 8-aminoquinoline NC9H6-8-NHLi. The elimination of alkane under the action of amidine 1 on Y(CH2SiMe3)2(THF)2 in THF affords bis(alkyl) yttrium complex [NC9H6-8- NC(But)N-2,6-Pri 2-C 6H3]Y(CH2SiMe3)2(THF) (2), monomeric in the crystalline state.
