160911-73-9Relevant academic research and scientific papers
Rhodium-Catalyzed Decarbonylative Borylation of Aromatic Thioesters for Facile Diversification of Aromatic Carboxylic Acids
Ochiai, Hidenori,Uetake, Yuta,Niwa, Takashi,Hosoya, Takamitsu
, p. 2482 - 2486 (2017/02/23)
Transformation of aromatic thioesters into arylboronic esters was achieved efficiently using a rhodium catalyst. The broad functional-group tolerance and mild conditions of the method have allowed for the two-step decarboxylative borylation of a wide range of aromatic carboxylic acids, including commercially available drugs.
From carboxylic acids to the trifluoromethyl group using BrF3
Cohen, Or,Mishani, Eyal,Rozen, Shlomo
experimental part, p. 3579 - 3582 (2010/07/04)
Organic trifluoromethyl derivatives were made from aromatic and aliphatic carboxylic acids by transforming them first into the corresponding dithioesters followed by reaction with bromine trifluoride under mild conditions (0 °C, 2 min).
A Novel Method for Converting Aromatic Acids into Trifluoromethyl Derivatives using BrF3
Rozen, Shlomo,Mishani, Eyal
, p. 2081 - 2082 (2007/10/02)
Aryltrifluoromethyl derivatives are obtained in good yields from the corresponding aryl carboxylic acids by reacting their dithionic esters with BrF3 under very mild conditions.
