1609120-08-2

Basic information

• Product Name: 1-(4-tolylthio)naphthalen-2-yl triflate
• Synonyms: 1-(4-tolylthio)naphthalen-2-yl triflate
• CAS NO: 1609120-08-2
• Molecular Weight: 398.427
• Mol File: 1609120-08-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-(4-tolylthio)naphthalen-2-yl triflate(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(4-tolylthio)naphthalen-2-yl triflate(1609120-08-2)
• EPA Substance Registry System: 1-(4-tolylthio)naphthalen-2-yl triflate(1609120-08-2)

Safety Data

• Hazardous Substances Data: 1609120-08-2(Hazardous Substances Data)

Upstream product

• 799764-32-2 1-(4-methylphenylsulfenyl)naphthalen-2-ol 
• 2943-42-2 di(4-methyl)phenylthiosulfonate 
• 573-97-7 1-bromo-2-naphthol 

Downstream Products

• 1609120-09-3 1-(4-tolylsulfinyl)naphthalen-2-yl triflate 
• 138719-98-9 7,12-diphenyl-7,12-dihydro-7,12-epoxybenz[a]anthracene 

Relevant articles and documents

Generation of arynes triggered by sulfoxidemetal exchange reaction of ortho-sulfinylaryl triflates

Arynes were efficiently generated from readily available ortho-sulfinylaryl triflates by the treatment with phenylmagnesium bromide in tetrahydrofuran at 78 C. Aryne generation was initiated by a rapid sulfoxidemetal exchange reaction, followed by the immediate elimination of the ortho-OTf group. Various arynophiles efficiently reacted with arynes generated by this method within 10min, providing the corresponding adducts in high yields.