1609120-83-3Relevant academic research and scientific papers
Pd(II)-catalyzed selective sulfenylation of arene C-H bonds using N-arylthiobenzamides as thiolation reagent and oxidant
Zhang, Xing-Song,Li, Guoxing,Zhang, Xing-Guo,Zhang, Xiao-Hong
, p. 5458 - 5464 (2015/08/03)
The palladium-catalyzed direct sulfenylation of arenes with N-arylthiobenzamides was developed for the synthesis of aryl sulfides. Additional oxidant was not required for the catalytic cycle because N-arylthiobenzamide was used as both thiolation reagent and oxidant. The selective mono- or di-sulfenylation could be controlled by addition of the amount of N-arylthiobenzamide. Excellent functional group tolerance was observed and thioethers or dithioethers were obtained in good yields.
Palladium-catalyzed direct thiolation of aryl C-H bonds with disulfides
Iwasaki, Masayuki,Iyanaga, Miki,Tsuchiya, Yuta,Nishimura, Yugo,Li, Wenjuan,Li, Zhiping,Nishihara, Yasushi
supporting information, p. 2459 - 2462 (2014/03/21)
A catalytic variant of the direct thiolation of arenes, bearing directing groups, with disulfides or thiols has been developed under palladium and copper co-catalysis. Both sulfenyl moieties of the disulfide could be incorporated into the thiolated produc
