1609162-85-7Relevant academic research and scientific papers
Thioether-ligated iron(ii) and iron(iii)-hydroperoxo/alkylperoxo complexes with an H-bond donor in the second coordination sphere
Widger, Leland R.,Jiang, Yunbo,McQuilken, Alison C.,Yang, Tzuhsiung,Siegler, Maxime A.,Matsumura, Hirotoshi,Moenne-Loccoz, Pierre,Kumar, Devesh,De Visser, Sam P.,Goldberg, David P.
, p. 7522 - 7532 (2014)
The non-heme iron complexes, [FeII(N3PySR)(CH 3CN)](BF4)2 (1) and [FeII(N3Py amideSR)](BF4)2 (2), afford rare examples of metastable Fe(iii)-OOH and Fe(iii)-OOtBu complexes containing equatorial thioether ligands and a single H-bond donor in the second coordination sphere. These peroxo complexes were characterized by a range of spectroscopic methods and density functional theory studies. The influence of a thioether ligand and of one H-bond donor on the stability and spectroscopic properties of these complexes was investigated. This journal is the Partner Organisations 2014.
