1609170-37-7

Basic information

• Product Name: N-methyl-N′-(2-hydroxybenzylidene)-2-(6-methoxynaphthyl)-propane hydrazide
• CAS NO: 1609170-37-7
• Molecular Weight: 362.428
• Mol File: 1609170-37-7.mol

Chemical Properties

• CAS DataBase Reference: N-methyl-N′-(2-hydroxybenzylidene)-2-(6-methoxynaphthyl)-propane hydrazide(CAS DataBase Reference)
• NIST Chemistry Reference: N-methyl-N′-(2-hydroxybenzylidene)-2-(6-methoxynaphthyl)-propane hydrazide(1609170-37-7)
• EPA Substance Registry System: N-methyl-N′-(2-hydroxybenzylidene)-2-(6-methoxynaphthyl)-propane hydrazide(1609170-37-7)

Safety Data

• Hazardous Substances Data: 1609170-37-7(Hazardous Substances Data)

Upstream product

• 74-88-4 methyl iodide 

Relevant articles and documents

N-2-Hydroxybenzaldehyde acylhydrazone-Fe(iii) complex: Synthesis, crystal structure and its efficient and selective N-methylation

N-Methyl-N′-2-hydroxybenzaldehyde acylhydrazones have been chemospecifically synthesized in good yield by N-methylation of the Fe(iii) complexes of N-2-hydroxybenzaldehyde acylhydrazones with methyl iodide in tetrahydrofuran. The reaction proceeds with the exclusive formation of the N-methyl derivative without any concurrent O-methylation side reactions. In addition, the N-methylation reaction occurred simultaneously with a complete deprotection step (elimination of the metal ion). As a result, the N-methyl product was obtained in excellent purity without time-consuming chromatographic workup. A free N-2-hydroxybenzaldehyde acylhydrazone ligand could not be methylated under the same conditions. This journal is the Partner Organisations 2014.