1609171-52-9

Basic information

• Product Name: N-phenyl-N-(3-(trifluoromethyl)phenyl)naphthalene-1-amine
• Synonyms: N-phenyl-N-(3-(trifluoromethyl)phenyl)naphthalene-1-amine
• CAS NO: 1609171-52-9
• Molecular Weight: 363.382
• Mol File: 1609171-52-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-phenyl-N-(3-(trifluoromethyl)phenyl)naphthalene-1-amine(CAS DataBase Reference)
• NIST Chemistry Reference: N-phenyl-N-(3-(trifluoromethyl)phenyl)naphthalene-1-amine(1609171-52-9)
• EPA Substance Registry System: N-phenyl-N-(3-(trifluoromethyl)phenyl)naphthalene-1-amine(1609171-52-9)

Safety Data

• Hazardous Substances Data: 1609171-52-9(Hazardous Substances Data)

Upstream product

• 101-23-5 N-(3-trifluoromethylphenyl)aniline 
• 90-11-9 1-Bromonaphthalene 
• 90-13-1 1-Chloronaphthalene 

Relevant articles and documents

Synthesis of sterically congested triarylamines by palladium-catalyzed amination

An efficient protocol for the palladium-catalyzed synthesis of sterically congested triarylamines from commercially available 1-chloro- or 1-bromonaphthalenes and diarylamines is described. The application of alkyllithium reagents as strong bases and a combination of Pd(OAc)2 and SPhos (2-dicyclohexylphosphino-2′,6′-dimethoxybiphenyl) plays a crucial role in the success of this otherwise difficult to achieve C-N coupling reaction. A variety of secondary aromatic amines with versatile steric and electronic properties can be successfully used in this transformation to give the desired triarylamines in up to 99 % yield. The obtained products are important structural motifs in hole-transport materials for organic light-emitting diode applications. A variety of secondary aromatic amines are coupled with 1-halonaphthalenes to give sterically highly congested triarylamines in up to 99 % yield. The key to the success of this transformation is prior deprotonation of the amine with strong bases such as n-hexyllithium. Copyright