1609243-93-7Relevant academic research and scientific papers
Rhodium(III)-catalyzed intramolecular redox-neutral annulation of tethered alkynes: Formal total synthesis of (±)-goniomitine
Zhou, Bing,Du, Juanjuan,Yang, Yaxi,Li, Yuanchao
, p. 12768 - 12772 (2015/03/30)
A RhIII-catalyzed intramolecular redox-neutral atom-economic annulation of a tethered alkyne has been developed to efficiently construct 2-amidealkyl indoles with completely reversed regioselectivity by a C-H activation pathway. Furthermore, us
Dirhodium(II) carboxylate catalyzed formation of 1,2,3-trisubstituted indoles from styryl azides
Jones, Crystalann,Nguyen, Quyen,Driver, Tom G.
, p. 785 - 788 (2014/01/23)
Dirhodium(II)-carboxylate complexes were discovered to promote the selective migration of acyl groups in trisubstituted styryl azides to form 1,2,3-trisubstituted indoles. The styryl azides are readily available in three steps from cyclobutanone and 2-iod
