1609386-45-9Relevant academic research and scientific papers
Alkene-assisted nickel-catalyzed regioselective 1,4-addition of organoboronic acid to dienones: A direct route to all-carbon quaternary centers
Hong, Ya-Chun,Gandeepan, Parthasarathy,Mannathan, Subramaniyan,Lee, Wei-Tse,Cheng, Chien-Hong
supporting information, p. 2806 - 2809 (2014/06/23)
A nickel-catalyzed highly regioselective 1,4-addition reaction of boronic acids to dienones to form products with an all-carbon quaternary center is described. The 3-alkenyl group of dienones is the key for the reaction to proceed smoothly. A mechanism involving the coordination of the dienyl group to the nickel center is proposed.
