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Relevant academic research and scientific papers

Aerobic oxidative C-H olefination of cyclic N-sulfonyl ketimines catalyzed by a rhodium catalyst

A useful method for the synthesis of ortho-olefinated ketimines from readily accessible cyclic N-sulfonyl ketimines and various olefins has been achieved. The reactions proceeded by Rh(III)-catalyzed, N-sulfonyl ketimine-directed C-H cleavage under aerobic conditions. Further synthetic transformations of the olefinic products led to interesting heterocyclic molecules.