1609556-16-2

Basic information

• Product Name: C₁₄H₁₉BrSi
• Synonyms: C₁₄H₁₉BrSi
• CAS NO: 1609556-16-2
• Molecular Weight: 295.294
• Mol File: 1609556-16-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₉BrSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₉BrSi(1609556-16-2)
• EPA Substance Registry System: C₁₄H₁₉BrSi(1609556-16-2)

Safety Data

• Hazardous Substances Data: 1609556-16-2(Hazardous Substances Data)

Upstream product

• 1000578-18-6 2-bromo-1-iodo-4-isopropylbenzene 
• 1066-54-2 trimethylsilylacetylene 

Relevant articles and documents

Enantioselective Alkoxycyclization of 1,6-Enynes with Gold(I)-Cavitands: Total Synthesis of Mafaicheenamine C

Chiral gold(I)-cavitand complexes have been developed for the enantioselective alkoxycyclization of 1,6-enynes. This enantioselective cyclization has been applied for the first total synthesis of carbazole alkaloid (+)-mafaicheenamine C and its enantiomer, establishing its configuration as R. The cavity effect was also evaluated in the cycloisomerization of dienynes. A combination of experiments and theoretical studies demonstrates that the cavity of the gold(I) complexes forces the enynes to adopt constrained conformations, which results in the high observed regio- and stereoselectivities.

Transition-metal-mediated three-component cascade cyclization: Selective cage B-C(sp2) coupling of carborane with aromatics and synthesis of carborane-fused tricyclics

Zirconium/nickel comediated one-pot three-component cascade cyclization of carboryne, alkene, and 2-bromophenyltrimethylsilylacetylene has been achieved, leading to the formation of a series of C,C,B-substituted carborane-fused tricyclics. On the basis of