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The complex [(η6-p-Cymen)ruthenium(Cl)((5-pentafluorophenyl)dipyrrin)] is a fluoro-dipyrrin-based arene ruthenium(II) compound, analogous to the synthesized complex [(η6-C10H14)RuCl(PFPdpm)] (3), where the pentafluorophenyl-substituted dipyrrin ligand serves as a key structural and functional component. Such complexes exhibit potential biological activity, including DNA-binding properties and cytotoxicity, suggesting their relevance in medicinal chemistry, particularly for antitumor applications. The pentafluorophenyl group enhances reactivity, enabling post-functionalization for further derivatization, as demonstrated in related dipyrrinato metal complexes.

1609575-00-9

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1609575-00-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1609575-00-9 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,6,0,9,5,7 and 5 respectively; the second part has 2 digits, 0 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1609575-00:
(9*1)+(8*6)+(7*0)+(6*9)+(5*5)+(4*7)+(3*5)+(2*0)+(1*0)=179
179 % 10 = 9
So 1609575-00-9 is a valid CAS Registry Number.

1609575-00-9Relevant academic research and scientific papers

Pre-/post-functionalization in dipyrrin metal complexes-antitumor and antibacterial activity of their glycosylated derivatives

Gutsche, Claudia S.,Gr?fe, Susanna,Gitter, Burkhard,Flanagan, Keith J.,Senge, Mathias O.,Kulak, Nora,Wiehe, Arno

, p. 12373 - 12384 (2018)

A post-functionalization route to tris(dipyrrinato) metal complexes is presented giving access to a range of new complexes relevant in the context of medicinal inorganic chemistry. A pentafluorophenyl group in the meso-position of the dipyrrin ligand serves as an anchor for the connection with alcohols and thiocarbohydrates. The photochemotherapeutic activity of the complexes has been assessed in cellular assays with tumor cell lines and against the Gram-positive bacterium S. aureus. Finally, it is shown that this post-functionalization is also applicable to other dipyrrinato metal complexes.

Synthesis, characterization, DNA binding and cytotoxicity of fluoro-dipyrrin based arene ruthenium(II) complexes

Paitandi, Rajendra Prasad,Singh, Roop Shikha,Mukhopadhyay, Sujay,Sharma, Gunjan,Koch, Biplob,Vishnoi, Pratap,Pandey, Daya Shankar

, p. 117 - 127 (2017)

Synthesis of four new arene ruthenium(II) complexes [(η6-C10H14)RuCl(MFPdpm)] (1); [(η6-C12H18)Ru-Cl(MFPdpm)] (2); [(η6-C10H14)RuCl(PFPdpm)] (3) and [(ηsup

Near-IR photoresponse of ruthenium dipyrrinate terpyridine sensitizers in the dye-sensitized solar cells

Li, Guocan,Yella, Aswani,Brown, Douglas G.,Gorelsky, Serge I.,Nazeeruddin, Mohammad K.,Graetzel, Michael,Berlinguette, Curtis P.,Shatruk, Michael

supporting information, p. 5417 - 5419 (2014/06/23)

Coordination of bidentate 5-pentafluorophenyldipyrrinate (pfpdp) or 5-(2-thienyl)dipyrrinate (2-tdp) to a RuII center bearing 2,2:6,2″-terpyridine-4,4,4″-tricarboxylate (tctpy) and a NCS - ligand results in strongly light-absorbing complexes [Ru(tctpy)(L)(NCS)] (L = pfpdp or 2-tdp). Anchored to a mesoporous TiO 2 electrode, these complexes afford a photoaction spectral response at wavelengths of up to 950 nm, one of the most red-shifted values reported to date for molecular dyes in the dye-sensitized solar cell (DSSC).

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